| classical | non-classical |
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These structures are NOT equivalent in any sense, and in fact they can both be optimized with quantum chemical calculations. The structures shown below are optimized at the ab initio 3-21G level, with the classical more stable than the non-classical by about 0.5 kcal/mol.
| classical | non-classical | |
The non-classical cation is, in fact, the transition state for the alkyl shift shown below: